Irganox 3114 pdf file

Consequently, kinetic rate constants of s1 reaction would be on the same order of magnitude for a given family of stabilizer. The microlab pc software method, polymer irganox 3114 in polypropylene v1, includes the calibration data from figure 2. The perception of metallic stearates as acid acceptors. It has good compatibility, high resistance to extraction and low volatility. Massachusetts general hospital, harris orthopedic laboratory, boston, ma. It has good compatibility with most substrates, high resistance to extraction, and low volatility. Nov 01, 2012 blooming of irganox 3114 antioxidant onto a medical grade elastomer.

Oxidative stability of irradiated uhmwpe stabilized with. Tievk 1025 e september 2010 page 2 of 2 irganox 1076 p irganox 1076 is recommended for styrene homo and copolymers at a concentration level ranging from 0. Irganox md 1024 by basf is a metal deactivator and primary phenolic antioxidant. Yagoubi, blooming of irganox 3114 antioxidant onto a medical grade elastomer. Create and edit configurations live or off the line and save in a reference honeyell for future use or to download to other controllers.

In the work presented a systematic study has been undertaken on the stability of five selected commercial plastics additives irganox 3114, irganox 1035, irganox 245, irganox. It contains 1,3,5tris3,5ditertbutyl4hydroxybenzyl1,3,5triazine2,4,61h,3h,5htrione. Irganox 3114 pdf get instant access to irganox technical datasheet. It protects these substrates against thermooxidative degradation and contributes to their light stability. Determination of antioxidants irganox 1076 and irganox. For sample preparation liquidliquid extraction with lowtemperature purification combined with. Identification of the substancepreparation and the companyundertaking. Determination of irganox 3114 in polypropylene by infrared. Characterization irganox 1076, a sterically hindered phenolic antioxidant, is a highly efficient, non discoloring stabilizer for organic substrates such as plastics, synthetic fibers, elastomers, adhesives, waxes, oils and fats. Impact of the recrystallization conditions on the antioxidant polymorphism, on the film wettability and on. The comparative antioxidant effectiveness of phenolic. Determination of antioxidants irganox 1076 and irganox 1010. Provides unmatched extraction resistance and processing stabilization. Characterization irganox 3114 a sterically hindered phenolic antioxidant is a highly effec tive, non discoloring stabilizer for organic substrates such as polymers, syn thetic fibers, elastomers, adhesives, waxes, oils and fats.

Characterization irganox md 1024 is a metal deactivator and primary phenolic antioxidant chemical name 2,3bis33,5ditert. Migration of tinuvin p uv stabilizer and irganox 3114 antioxidant from highdensity polyethylene hdpe was studied. Migration of tinuvin p uv stabiliser and irganox 3114 antioxidant from high density polyethylene hdpe was studied. Impact of the recrystallization conditions on the antioxidant. Determination of irganox 3114 in polypropylene by infrared spectroscopy. Permits reduced losses under high temperature operating conditions. Additive library list id type a antioxidant b c metal deactivator d stabilizer g lubricant h plasticizer i antistatic additive j anticlouding agents. Autoxidation may be initiated by heat, high energy radiation such as ultraviolet light, mechanical stress, or through reaction with other impurities. Get instant access to irganox 3114 technical datasheet.

Concentration levels of irganox 1076 in hot melt adhesives range from 0. The sample must be pressed into a film or coupon prior to the analysis. Extensive performance data of irganox 1010 in various organic polymers and applications are available upon request. The 1076 can be observed at times in some of the chromatograms for the resins. Hansen solubility parameters can help you find a wide range of products that are predicted to be compatible with irganox 3114. This material is not intended for use in products for which prolonged contact with mucous membranes, body fluids or abraded skin, or implantation within the human body, is specifically intended, unless the finished product has been tested in. Since all hdpe sheets contained either tinuvin p or irganox 3114 never their mixture, all migration experiments proved the lack of either irganox 3114 or tinuvin p in both. Their corresponding structures are shown in figure 1, together with their trade. Irganox 1010 would lead to assess ks1 irganox 1010. Irganox 3114 by basf is a sterically hindered phenolic antioxidant for processing and longterm thermal stabilization. A simple and fast analytical method was developed for the determination of six uv stabilizers cyasorb uv1164, tinuvin p, tinuvin 234, tinuvin 326, tinuvin 327, and tinuvin 1577 and five antioxidants irgafos 168, irganox 1010, irganox 3114, irganox 3790, and irganox 565 in milk. Used for wire and cable resins, filled polyolefins and nbr fuel hoses. Acts as a highly effective, nondiscoloring stabilizer. Irganox 3114 basf adhesives ingredients specialchem.

Impact of the recrystallization conditions on the antioxidant polymorphism, on the film wettability and on the antioxidant leachability, international journal of pharmaceutics, 2012, 437, 12, 89 crossref. Process and thermal stabilizers for specialty polymers. In a three month study, rats were administered dietary concentrations of 0, 150, 800, 3,000 and 15,000 ppm. It is a sterically hindered phenolic primary antioxidant. N n n o o o oh oh ho physical properties appearance. Mar 23, 2020 irganox 3114 ff by basf is a sterically hindered phenolic antioxidant.

The structures of these compounds are illustrated below. Pdf monitoring the degradation of stabilization systems in. Blooming of irganox 3114 antioxidant onto a medical grade. Irganox 3114 ciba sc cyanox 1741 cytec anox ic14 chemtura molecular formula. It has synergistic effect with uv adsorbent or phosphite ester to improve the stability. While irganox 30, irganox 3114 and cyanox 1790 showed a similar degradation mechanism with highly colored decomposition products. Basf irganox 1076 basf irganox 1076 is a high molecular weight sterically hindered phenolic antioxidant specifically recommended for use as a non discoloring stabilizer for organic substrates such as plastics, synthetic fibers, elastomers, adhesives, waxes, oils and fats. Chromatogram of pe with irganox 1076 obtained by thermal desorption. It protects substrates against thermooxidative degradation and contributes to light stability. It is a highly effective, nondiscoloring stabilizer. Impact of the recrystallization conditions on the antioxidant polymorphism, on the film wettability and on the antioxidant leachability. Polypropylene homopolymer formulation, from customer, extracted by ultrasonic according to the method astm d604204 3. Phenolic primary antioxidant for processing and longterm thermal stabilization. Irganox 3114 has low volatility and high resistance to extraction.

Section c information about the deceased persons spouse. Pentaerythritol tetrakis3,5ditertbutyl4hydroxyhydrocinnamate 2 product results. Jul 15, 2019 irganox 3114 pdf get instant access to irganox technical datasheet. Application for death benefits omb number 32060172 federal employees retirement system. Tris3,5ditertbutyl4hydroxybenzyl isocyanurate equivalent. Plaox 3114 is one kind of multifunctional antioxidant, with multiple functional groups. Basf irganox l 115 is a high molecular weight phenolic antioxidant containing a thioether group. Sds of antioxidant 3114, safety data sheets, cas 27676626. This calibrated method is available with the agilent 5500 and 4500 series dialpath or tumblir ftir spectrometers, as well as the cary 630 ftir spectrometers.

Applying for death benefits under the federal employees retirement system this pamphlet is for use by persons applying for benefits which may be payable under the federal employees retirement system fers because of the death of an employee, former employee, or retiree who was covered by fers at the time of hisher death. Mar 23, 2020 irganox 3114 by basf is a nondiscoloring, odorless, highly effective, sterically hindered phenolic antioxidant. This value would be very close ratio is less than one decade to the one for others hindered phenols. It is of low toxicity and can be used in food packing. The thermal stabilizing efficiency of a range of phenolic antioxidants lowi nox ca22, lowinox wsp, lowinox tbp6, irganox 3114, irganox 30.

The rats were observed for 14 days for signs of toxicity and mortality. Migration of tinuvin p and irganox 3114 into milk and the. High energy gas cluster ions for organic and biological. It contains 2,3bis 33,5ditertbutyl4hydroxyphenylpropionylpropionohydrazide. Safety data sheet according to directive 91155eec irganox 245 revision 05. Concentration levels of irganox 1010 in hot melt adhesives range from 0. Using the standard addition method, the concentrations of irganox 1076 and irganox 1010 were respectively determined to be 374 ppm 10% error and 429 ppm 9% error. Structure, properties, spectra, suppliers and links for. Blooming of irganox 3114 r antioxidant onto a medical grade. In addition to the usual hindered phenolic type antioxidants such as irganox 1010, 1076, and 3114, many of the resins contained phosphite esters such as irgafos 168 and ultranox 626. If you did not receive the pamphlet and the deceased was a federal.

Plaox 3114 is used in abs resin, polyester, nylon, pe, ps, pvc, pu, cellulose plastic and rubber. Irganox 3114 by basf is a nondiscoloring, odorless, highly effective, sterically hindered phenolic antioxidant. A process as claimed in claim 1 or 2 wherein said at least one organic phosphite or phosphonite antioxidant is selected from bis 2methyl4,6bis 1,1dimethylethyl phenyl phosphorous acid ethylester, tris 2,4di t butylphenyl phosphite, trisnonylphenyl. Irganox 3114 p 784 218 223 n nondiscoloring phenolic ao.

Irganox 3114, irganox 1010, vitamin e, irganox 1076, and irgafos168, all 200. Irganox 3114 cibageigy, adk stab ao20adeka, gsy314mitsubishi pharma, anox ic14enichem 784. Information from its description page there is shown below. It is a sterically hindered phenolic antioxidant which protects against thermooxidative degradation. Request pdf blooming of irganox 3114 r antioxidant onto a medical grade elastomer.

Influence of trace aluminum in low density polyethylene discoloration from the reactivity of hydroxy substituted benzophenone with trace aluminum. Mar 28, 2020 irganox 3114 pdf get instant access to irganox technical datasheet. Applying for death benefits under the federal employees. Extractables and leachables from single use bioprocess. Analysis of potential migrants from plastic materials in. In an oral acute study on rats, five males and five females were given 5000 mgkg of irganox 1076 in polyethylene glycol 400 20 mljkg bw by oral gavage. Product forms irganox 3114 white, freeflowing powder irganox 3114 ff white, freeflowing granules guidelines for use in polyolefins, the concentration levels for irganox 3114 range typically between 0. There were no treatmentrelated changes in blood chemistry, organ weights or urinalysis. Macroscopic and microscopic examination did not reveal treatmentrelated effects.

We have included irganox 1010 and irganox 1076 from ciba specialty chemicals as reference structures for comparison with the commercial hindered phenols. Aug 01, 2019 irganox 3114 pdf get instant access to irganox technical datasheet. Antioxidant 3114 recommended use of the chemical and restriction on use unsuitable for use. Aqueous suspension of irganox 245 as aochainstopper for pvc polymerization. Technical preparation of purest polymer is simply not. Fast analysis of phenolic antioxidants and erucamide slip.